Distribution of mercury in modern bottom sediments of the Beaufort Sea in relation to the processes of early diagenesis: Microbiological aspect.

This study investigated the contents of total mercury (THg), trace metals, and CH4 and determined the signature microbes involved in various biogeochemical processes in the sediment of the Canadian Beaufort Sea. The THg ranged between 32 and 63 µg/kg and the trace metals such as Fe, Al, Mn, and Zn were significant in distributions. The pH, SO42-, Fe2+, and redox proxy metals were crucial factors in the spatial and vertical heterogeneity of geochemical distributions. CH4 was detected only at the mud volcano site. Microbial analyses identified Clostridium, Desulfosporosinus, Desulfofustis, and Desulftiglans as the predominant Hg methylators and sulfate reducers; Nitrosopumilus and Hyphomicrobium as the major nitrifiers and denitrifiers; Methanosarcina and Methanosaeta as keystone methanogens; and Methyloceanibacter and Methyloprofundus as signature methanotrophs. Altogether, this study expands the current understanding of the microbiological and geochemical features and could be helpful in predicting ecosystem functions in the Canadian Beaufort Sea.

Human health risk assessment based on a total diet study of daily mercury intake in Chengdu, China.

To assess the total daily mercury intake and main exposure sources of residents, six food groups, including marine fish, freshwater fish, poultry, livestock, vegetables, and cereals, were collected from five districts of Chengdu, China. The median concentrations of total mercury (THg) and methylmercury (MeHg) were 12.8 and 6.94 µg kg-1 ww, respectively. Cereals (32.2%), vegetables (30.5%), and livestock (16.2%) contributed to a much larger extent to the total consumption for the participants in Chengdu. All food categories that contributed the most of THg (2.16 µg day-1) and MeHg 1.44 (µg day-1) to the daily intake in Chengdu were cereals and marine fish, respectively. The total Hazard Ratios values below 1 in this study indicate that there is no health risk associated with Hg ingestion from the consumption of these foods for the residents in Chengdu.

Effect of environmental variables on mercury accumulation in sediments of an anthropogenically impacted tropical estuary (Buenaventura Bay, Colombian Pacific).

Estuaries are the main entry areas of mercury to the marine environment and are important to understand the effect of this contaminant on marine organisms, since it accumulates in the sediments becoming available to enter the food trophic chain. This study aims to determine the environmental variables that mainly influence the spatiotemporal dynamics of total mercury accumulation in sediments of tropical estuaries. Sediment samples were collected from interior and exterior areas of the estuary during the dry and rainy seasons, representing the spatiotemporal gradients of the estuary. The grain size, organic matter content (OM), and total mercury concentration (THg) of the sediment samples were determined. In addition, salinity, temperature, dissolved oxygen, and pH of the water column associated with each sediment sample were assessed. The variations in environmental conditions, OM and THg in sediment were in accordance with a gradient which goes from conditions influenced by fresh water in the inner estuary to conditions influenced by sea water in the outer part of the estuary. The OM and THg in sediments presented similar variation patterns; they were higher in the rainy season than in the dry season and in the interior area of the estuary than in the exterior area. Despite the complex dynamic observed in the distribution and accumulation processes of mercury in sediments, these processes could be modeled from OM and salinity parameters. Due to the correlations found, in the process of accumulation of mercury in sediments the OM could represents the pathway of transport and accumulation of THg, and salinity could represent the influence of the hydroclimatic variations and environmental gradients of the estuary.

Methylmercury and mercury in Mediterranean mussels (Mytilus galloprovincialis) from Turkish coast: Dietary exposure prediction.

The spatial distribution of total mercury (HgT) and methylmercury (MeHg) in Mediterranean mussels (Mytilus galloprovincialis) sampled at 23 different stations along Türkiye's Black Sea, the Marmara, and Aegean Sea coasts were investigated in this study. HgT and MeHg were determined using a direct mercury analyzer and ranged 1.10-130.70 µg/kg and 0.22-37.90 µg/kg dry weight, respectively. HgT and MeHg have been determined to have a substantial positive correlation (r2 = 0.94). According to average consumption and portion sizes, the weekly intake (EWI) for MeHg was less than the 1.6 µg/kg/week limits set by the FAO/WHO Joint Committee of Experts on Food Additives (JECFA) for both pediatric and adult consumers. The Target Risk Coefficients (THQ) were calculated to explain the potential long-term exposure scenarios. Our data showed that the excessive consumption of mussels from areas with high MeHg concentrations might pose a risk only for pediatric consumers. The determination of suitable sites for healthy-sustainable mussel production as well as the prevention of collecting mussels from illegal and polluted fields and placing them on the market, should be considered in the context of consumer health awareness.

Distributions of total mercury and methylmercury and regulating factors in lake water and surface sediment in the cold-arid Wuliangsuhai Lake region.

This study aimed to understand the occurrence of mercury in the water environment of typical cold and arid lakes and the regulating environmental factors. Water and surface sediment samples were collected from July to August, 2022 in the Wuliangsuhai Lake region for the analysis of total mercury (THg) and total methylmercury (TMeHg). Lake water THg and TMeHg ranged between 19.20 ~ 668.10 and 0.10 ~ 11.40 ng/L, respectively, exceeding China's environmental quality standards and contents of other lakes and reservoirs in China and other areas. Surface sediments showed lower mean THg and TMeHg of 261.85 and 0.18 µg/kg, respectively, with the former significantly exceeding the background value of Inner Mongolia and unpolluted natural lakes but lower than those of lakes affected by human factors, such as aquaculture. Sediments showed relatively low methylation and TMeHg (0.01-0.21%) concentrations. Correlation analysis identified salinity, total dissolved solids, conductivity, and redox potential as important factors affecting mercury speciation in water, whereas those in surface sediments were organic matter, pH, and total iron content. This study conducted preliminary research on the different species of Hg in Wuliangsuhai Lake water environment, which can provide scientific evidence for the specific treatment of Hg pollution in agriculture, or industry and other related fields. Our results suggest that upstream and downstream regulatory agencies should strengthen the regulation of agricultural and industrial production, moderately reduce human activities, and reduce the use of mercury-rich substances such as pesticides.

Mercury and amino acid content relations in northern pike (Esox lucius) in subarctic lakes along a climate-productivity gradient.

Mercury is a highly toxic element for consumers, but its relation to amino acids and physiology of wild fish is not well known. The main aim of this study was to evaluate how total mercury content (THg) of northern pike (Esox lucius) is related to amino acids and potentially important environmental and biological factors along a climate-productivity gradient of ten subarctic lakes. Linear regression between THg and sixteen amino acids content [nmol mg-1 dry weight] from white dorsal muscle of pike from these lakes were tested. Lastly, a general linear model (GLM) for age-corrected THg was used to test which factors are significantly related to mercury content of pike. There was a positive relationship between THg and proline. Seven out of sixteen analysed amino acids (histidine, threonine, arginine, serine, glutamic acid, glycine, and aspartic acid) were significantly negatively related to warmer and more productive lakes, while THg showed a positive relationship. GLM model indicated higher THg was found in higher trophic level pike with lower cysteine content and inhabiting warmer and more productive lakes with larger catchment containing substantial proportion of peatland area. In general, THg was not only related to the biological and environmental variables but also to amino acid content.

Spatial distribution of Hg in Pra River Basin, Southwestern Ghana using HF acid combination method.

The study assessed the spatial distribution of total mercury (THg) in soils, sediments, mining wastes, and Au-rich Hg-contaminated tailings from artisanal and small-scale gold mining (ASGM) from Offin, Lower and Upper Pra, Birim, and Anum Rivers, Pra River Basin, Southwestern Ghana. THg measurement using Cold Vapor Atomic Absorption Spectrometry (CVAAS) after acid digestion with HNO3/HCl/HF and k0-INAA, as a reference method, and both provided comparable results. A digestion method, HNO3/HClO2/H2SO4 acid mixture before CVAAS provided lower results, which indicates that the use of HF is of fundamental importance in THg analysis based on acid digestion and its omission may significantly underestimate the presence of Hg in soils and sediments. THg in soils, sediments, Au-rich Hg-contaminated tailings, and mining wastes from the river basin were liberated into a solution for measurement using HNO3/HCl/HF. The study revealed Offin and Lower Pra Rivers showed high distribution (ranges; mg Hg kg-1) of THg in soils (103-770) and sediments (0.20-20.8), respectively; Upper Pra and Anum rivers showed the lowest THg in soils (2.20-3.20) and sediments (0.004-0.02), respectively. About 76.0% of THg in sediments was lower than the USEPA guideline of 0.2 mg Hg kg-1. The highest mean THg (mg Hg kg-1) in Au-rich Hg-contaminated tailings (1673 ± 4.8, n = 4) and mining wastes (17.3-21.5) were from the river Offin. The study showed Offin (Dunkwa-on-Offin site 1) and Lower Pra (Beposo Township) rivers are Hg hotspots that need attention.

Mercury assessment in invasive Lionfish Pterois (Oken, 1817) from marine protected areas in the Colombian Caribbean.

Lionfish (Pterois spp.) are invasive species reported since 2009 in the Corales del Rosario y San Bernardo National Natural Park in the Caribbean. Their capture and consumption are strategies to control their dispersion and limit ecological damage. The natural park is influenced by the vicinity of Cartagena's residential, industrial, and touristic activities, as well as sediments loaded with mercury from the Dique Channel. For the first time, total mercury levels in muscle from 58 lionfish were determined, with values ranging from 0.01 to 0.38 µg/g (mean = 0.11 ± 0.01 µg/g). Fish length ranged from 17.4 to 44.0 cm (mean = 28.0 ± 0.63 cm). Mercury levels did not increase proportionally to fish length for pooled data, but the relationship was significant for specimens from Rosario Island. Mercury levels comply with legislation for fish consumption, but the risk to human health may appear if it occurs daily. Therefore, precautionary approach and a permanent monitoring strategy are strongly advised.

Preindustrial levels and temporal enrichment trends of mercury in sediment cores from the Gulf of Thailand.

Four sediment cores in the middle of Gulf of Thailand (GOT) and one core close to Bang Pakong River mouth were examined for total mercury (T-Hg) using direct thermal decomposition coupled with the atomic absorption spectrometry (DTD-AAS) method and acid digestion (acid-CVAAS) method, and sediment chronologies using 210Pb dating. T-Hg in the river mouth core ranged 44.49-52.76 µg/kg and higher than the cores from the middle of GOT (18.26-36.68 µg/kg). The age span obtained from the cores dated back to the 1940s with the sediment accumulation rates of 0.15-0.76 cm/year. The preindustrial levels of T-Hg showed an initial slow increase followed by a rapid elevation since the 1960s which marked the start of the industrialized period in the country. To this end, we posit that T-Hg in the GOT sediment can be attributed to not only land-based sources but also offshore activities including petroleum exploration and frequent accidental oil spills.

Incorporating soil mercury species and fractions into multi-objective risk assessment of a residue disposal site in China.

Environmental problems in soil and water caused by solid waste dumps have become a growing concern. This study proposes an integrated risk assessment model aimed at multi-objectives including human, ecology and groundwater and develops remediation target values at different tiers associated with soil mercury species and fractions in a typical residue disposal site of China. The results show that the residue disposal site was severely contaminated with mercury, with the maximum mercury content in the soil reaching 579.14 mg/kg. The average concentration of vapour mercury, bioaccessible mercury, bioavailable mercury and leachable mercury tested in laboratory was 87.65 mg/kg, 3.15 mg/kg (intestinal phase), 1.654 mg/kg and 0.045 mg/L, respectively. The hazard index calculated using total mercury, bioaccessible mercury and vapour mercury was 7.43 E + 01, 4.42 E + 01, and the remediation target values were7.79 mg/kg and 13.1 mg/kg, respectively. The ecological risk for total mercury and bioavailable mercury was calculated using measured site soil mercury background values of 6390.92 and 94.52, and the remediation target was 0.7 mg/kg and 47.33 mg/kg, respectively. Under Class IV water conditions, the measured and three-phase equilibrium model simulations of leachable mercury resulted in remediation targets of 6 mg/kg and 10 mg/kg for soil mercury. Compared to total mercury, the remediation target values calculated using mercury species and fractions were significantly larger under human health protection, ecology protection and groundwater protection. This results in a reduction in the area of soil to be remediated by 20.3-85.7%, resulting in significant savings in remediation costs. It was concluded that when conducting risk assessment and reuse of mercury-contaminated sites, it is important to consider the species and fractions of mercury in the soil in order to reasonably determine the remediation criteria and scale of remediation to avoid over-remediation and incomplete remediation. At the same time, a comprehensive protection target remediation mechanism should be established by combining different receptors.

Mercury and other trace elements distribution and profiling of microbial community in the surface sediments of East Siberian Sea.

In this study, total mercury (THg), methylmercury (MeHg), various trace elements, and microbial communities were measured in surface sediments of the East Siberian Sea (ESS). The results showed that the average values of THg and MeHg were 58.8 ± 15.21 µg/kg and 0.50 ± 0.22 µg/kg, respectively. The notable levels of trace elements present in both surface sediment and porewater were Al, Fe, and Mn. The enrichment factor and geoaccumulation index analyses found that both natural phenomena and anthropogenic activities contributed to elevated concentrations of metals in the ESS. The redox proxy metals, pH, and SO42- were the major factors influencing the THg and MeHg distributions. Microbial profiles were substantially affected by metals and other abiotic factors. Proteobacteria and Thaumarchaeota were the most abundant phyla. Overall, the findings presented here facilitate the understanding of the current status of metal contamination, its influencing factors, and metal-microbiota-interactions in ESS.

Total and methylmercury concentrations in nocturnal migratory birds passing through Mount Ailao, Southwest China.

Despite growing concerns over mercury (Hg) accumulation in birds in recent decades, little is known about Hg exposure in nocturnal migratory birds. Here, total mercury (THg) and methylmercury (MeHg) were detected in the feathers of nocturnal migratory birds (n = 286, belonging to 46 species) passing through Mount Ailao in Southwest China. The stable isotope ratios of carbon (δ13C) and nitrogen (δ15N) were also determined to clarify the effects of trophic position, foraging guild, and foraging behavior on Hg bioaccumulation. Our results show that the THg and MeHg concentrations varied by two orders of magnitude among all nocturnal migratory birds investigated, with the lowest values (THg: 0.056 mg kg-1; MeHg: 0.038 mg kg-1) in the Asian koel (Eudynamys scolopaceus) and the highest (THg: 12 mg kg-1; MeHg: 7.8 mg kg-1) in the hair-crested drongo (Dicrurus hottentottus). Waterbirds showed higher δ15N values and higher THg and MeHg concentrations than songbirds, and the Hg concentrations in piscivorous species were significantly higher than those in herbivores, omnivores, and insectivores. Significant effects of foraging guilds (Kruskal-Wallis one-way ANOVA, p < 0.001) and foraging behaviors (Kruskal-Wallis one-way ANOVA, p < 0.001) on the Hg concentrations in migratory bird feathers were detected. A risk assessment indicated that approximately 7.0% of individuals were at moderate (2.4-5.0 mg kg-1) to high (>5.0 mg kg-1) risk of Hg exposure, and were therefore vulnerable to adverse physiological and behavioral effects. A long-term monitoring campaign during the migratory period is highly recommended to better understand the bioaccumulation of Hg in these nocturnal migratory bird populations over time.

Total Mercury and Fatty Acids in Selected Fish Species on the Polish Market: A Risk to Human Health.

The muscles of lake trout (Salvelinus namaycush Walbaum, 1792), crucian carp (Carassius carassius Linnaeus, 1758), flounder (Platichthys flesus Linnaeus, 1758), gilthead seabream (Sparus aurata Linnaeus, 1758), mackerel (Scomber scombrus Linnaeus, 1758) and tench (Tinca tinca Linnaeus, 1758) were examined. The total mercury (THg) was processed using the Milestone DMA-80 and the fatty acids were analyzed using the 7890A Agilent Technologies chromatograph. The THg content in analyzed fish ranged from 0.024 (lake trout) to 0.092 mg/kg wet weight (gilthead seabream). The muscles of fish examined had lower amounts of SFAs, and n-3 and n-6 PUFAs than MUFAs. The ratio of n-3/n-6 was higher in muscles of mackerel than other fish (p < 0.05). Due to the fact that both the THQ and HI are below 1, the tested fish are safe for the consumer from a nutritional point of view. Similarly, fatty acid indices indicate the safe consumption of selected fish species, and the daily consumption of the recommended dose of EPA + DHA (250 mg/day) and the concentration of mercury in fish calculations showed a hazard quotient for the benefit−risk ratio HQEFA below 1, suggesting that the intake of EPA + DHA poses no evident risk to human health. The ratio was calculated for a person weighing 60 kg. Therefore, it is important to monitor the fish, not only bought in the store, but also caught in various aquatic environments.

Mercury biomagnification in benthic, pelagic, and benthopelagic food webs in an Arctic marine ecosystem.

Mercury (Hg) is a ubiquitous toxic metal that biomagnifies in food webs, and can reach high concentrations in top predators. Evaluating Hg biomagnification in Arctic marine food webs is critical for understanding Hg dynamics and estimating exposure to understudied fish and wildlife consumed by humans. The majority of studies conducted on Hg biomagnification in the Arctic have focused on pelagic food webs. Benthic and benthopelagic food webs in Arctic marine ecosystems also support many species of subsistence and commercial importance, and data are lacking for these systems. In this study, we investigated food web structure and Hg biomagnification for the benthic, pelagic, and benthopelagic marine food webs of inner Frobisher Bay in Nunavut. Stable isotope ratios of carbon (δ13C) and nitrogen (δ15N), as well as total (THg) and methyl (MeHg) mercury concentrations were measured in fish, invertebrates, and zooplankton. Biomagnification in each food web was quantified with Trophic Magnification Slopes (TMS) and Trophic Magnification Factors (TMF). The highest TMS and TMF values were exhibited by the benthopelagic food web (TMS = 0.201; TMF = 1.59), followed by the pelagic food web (TMS = 0.183; TMF = 1.52), and lastly the benthic food web (TMS = 0.079; TMF = 1.20), with δ15N explaining 88%, 79%, and 9% of variation in Hg concentrations, respectively. TMS and TMF values were generally low compared to other Arctic marine food webs. Results from food web structure analyses indicated that the benthic food web had the greatest trophic diversity, trophic redundancy, and largest isotopic niche area of all food webs studied. Greater food web complexity may thus result in reduced MeHg biomagnification, but further study is required. Acquiring Hg and food web structure data is critical for predicting the effects of climate-induced environmental change on Hg dynamics, especially in the context of Arctic marine ecosystems.

[Survey of Total Mercury Content in Fishery Products].

The total mercury content in 112 fishery products, purchased from Osaka city during 2013-2018, was measured using a heating vaporization mercury analyzer. The average total mercury content in all tuna processed products was found out to be 0.115 µg/g (median=0.070 µg/g). Notably, albacore tuna exhibited the highest mercury content with an average concentration of 0.301 µg/g (median=0.296 µg/g). The total mercury concentration of the fishery products, except processed tuna and Kezuribushi (comprising shavings of dried and smoked mackerel, sardine, as well as horse mackerel), was generally low (<0.1 µg/g).The provisional tolerable weekly intake (PTWI) for mercury as set by the Joint FAO/WHO Expert Committee on Food Additives is 4.0 µg/kg body weight/week. On an average, for Japanese diet, the total weekly mercury intake from fishery products for a person weighing 50 kg was estimated to be 0.13 µg/kg body weight/week, which was 3.3% of the PTWI. These values indicate that it was not a problem to consume fishery products normally. However, albacore tuna cans have a relatively high total mercury concentration; thus, pregnant women consuming them daily may exceed the tolerable weekly intake of methylmercury (2 µg/kg body weight/week) as set by the Food Safety Commission of Japan.

Import, export, and speciation of mercury in Kongsfjorden, Svalbard: Influences of glacier melt and river discharge.

The major sources and sinks of total mercury (THg) and methylmercury (MeHg) in Kongsfjorden were estimated based on spreadsheet-based ecological risk assessment for the fate of mercury (SERAFM). SERAFM was parameterized and calibrated to fit Kongsfjorden using the physical properties of the fjord, runoff coefficients of Hg, transformation rate constants of Hg, partition coefficients of Hg, Hg loadings from freshwater, and solid balance parameters. The modeled Hg concentrations in the seawater matched with the measured concentrations, with a mean bias of 12% and a calibration error of 0.035. The mass budget showed that the major THg sources were tidal inflow and glacial runoff, while the major MeHg sources were tidal inflow and in situ methylation in shallow halocline water, which agreed with the distributions of THg and MeHg in seawater. The coupling of observation and fate modeling in Kongsfjorden provides a basic understanding of Hg cycles in the Arctic fjords.

Simple Acid Digestion Procedure for the Determination of Total Mercury in Plankton by Cold Vapor Atomic Fluorescence Spectroscopy.

Plankton, at the bottom of the food web, play a central role in the entry of mercury into the aquatic biota. To investigate their role in mercury uptake, reliable analytical procedures for Hg analysis are highly sought. Wet digestion procedures for determining total mercury in different biological matrices have been established since years, however only few studies focused on planktonic samples. In the present work, a simple and cost-effective wet digestion method was developed for the determination of total mercury in samples of small plankton material using a cold vapor atomic fluorescence spectroscopy (CVAFS). The optimization of the digestion method was achieved by using glass vessels with Teflon caps, low amount of acids (3 mL w/w 65% HNO3 or 3 mL 50% v/v HNO3), a constant temperature of 85 °C, the presence and absence of pre-ultrasound treatment, and a continuous digestion period (12 h). Certified reference materials IAEA-450 (unicellular alga Scenedesmus obliquus) and BRC-414 (plankton matrix) were used to optimize and validate the digestion method. The recovery efficiency of the proposed method for IAEA-450 and BCR-414 (3.1 mg and 21.5 mg) ranged between 94.1 ± 7.6% and 97.2 ± 4.6%. The method displayed a good recovery efficiency and precision for plankton matrices of low size. Thus, allowing better digestion of planktonic samples for mercury analysis using CVAFS techniques.

Ventral feathers contained the highest mercury level in brown booby (Sula leucogaster), a pantropical seabird species.

Seabirds are extensively used as environmental biomonitors and feathers are among the most analyzed matrices because they are one of the main excretory pathways to detoxify the bird's body of environmental contaminants. Still, there is a variation in contamination level between the different feathers of seabird species, driven by diet and physiology, such as molt strategy and feather formation sequence. We measured total mercury (THg) concentration in different types of feathers (wing, tail, ventral and dorsal) of the same individual in adults and juveniles of brown boobies (Sula leucogaster) from the northern coast of Rio de Janeiro state, Brazil. Brown booby had higher mean THg concentration (µg.g-1 d. w.) in ventral (adults: 6.46 ± 1.19, 4.79 to 8.34; juveniles: 4.23 ± 0.60, 3.07 to 5.07) and wing (adults: 5.85 ± 1.10, 4.66 to 8.32; juveniles: 3.86 ± 0.54, 3.23 to 4.63), compared to dorsal (adults: 4.52 ± 1.33, 3.01 to 6.44; juveniles: 3.51 ± 0.19, 3.29 to 3.8) and tail feathers (adults: 2.94 ± 0.45, 2.32 to 3.46; juveniles: 2.8 ± 0.23, 2.45 to 3.08). This difference may be explained because feathers grow in a specific sequence during molts leading to different THg concentrations in each type of feather. Additionally, juveniles had significantly lower concentrations of THg than adults in all feather types, which may be explained by the shorter life span, leading to less time to bioaccumulate Hg in their body. It is essential to choose carefully which feather type is more suitable to be used as a biomonitor of THg contamination in a particular species. For brown boobies, we suggest the use of ventral feathers, which represent the highest Hg concentration, are easy to sample and do not impair the seabird's flight ability, although more studies are needed to replicate these results in other tropical seabirds species.

Mercury levels in Merluccius merluccius muscle tissue in the central Mediterranean Sea: Seasonal variation and human health risk.

In this study we analysed total mercury (THg) levels in European hake (Merluccius merluccius) - an ecologically and commercially important species throughout the Mediterranean - caught in the northern and central Adriatic Sea. To the best of our knowledge, this is the first study evaluating THg levels in hake fillets in relation to ecological (season) and biological (body size, sex, sexual maturity, lipid content) parameters. THg levels in muscle showed no sex-related differences; in contrast, significant season-related differences were found in females, with higher levels in spring-summer compared with autumn-winter. No season-related differences were seen in males. A significant sex effect was found for body size and sexual maturity. Females showed a correlation between THg level and length, THg being significantly higher in mature compared with immature specimens. No significant sex effect was found for muscle lipid content, because a correlation between THg concentration and tissue lipids was found in both sexes. Since the mean THg concentration found in M. merluccius fillets (0.64 ± 0.29 mg kg-1 dry weight; range, 0.20-1.53) was consistently under the level set by EU regulations, this study demonstrates that European hake caught in the northern and central Adriatic is safe for human consumption.

Distribution and environmental geochemical indices of mercury in tar contaminated beaches along the coast of Qatar.

The current study aimed to gauge total mercury (THg) concentration and the environmental geochemical indices in tarmat contaminated sediments and test their presence in targeted coastal species. Layers of hard asphalt-like tarmats and sediment samples were collected from 34 sites along the coast of Qatar. The mean concentration of THg in tarmat-sediment mixture is 89 ± 20 ng·g-1. THg concentration varies significantly between the northern and eastern coasts. Geographically, sampling area were divided into four zones according to the relative closeness with low to serious potential ecological risk index (Er), moderate pollution load index (PLI), moderate Geoaccumulation index (Igeo), and no toxic risk (TRI) trending as Northern (Zones 4, 3) > North-Eastern (Zone 1) > Western (Zone 2) coasts. Three biota classes (Gastropoda, Bivalvia, and Crustacea) were sampled on the tarmat which the hermit crab (Clibanarius signatus) from Ras Rakan island obtained the highest THg (977 ng·g-1) and BSAF (29.70).